Application of controlled hydrolysis of titanium(IV) isopropoxide to produce sol-gel-derived thin films

Dilum D. Dunuwila, Charles D. Gagliardi, Kris A. Berglund

    Research output: Contribution to journalArticle

    • 51 Citations

    Abstract

    A variety of porous optically transparent titanium carboxylate films that can be supported on silicate glass substrates have been developed. These films were made by spin casting polymeric solutions of titanium carboxylates processed using sol-gel techniques. The stability and the quality of these films have been qualitatively correlated to the extent of control of hydrolysis exerted by carboxylate modification of the precursor titanium(IV) isopropoxide. A series of carboxylic acids ranging from acetic acid to myristic acid has been used, and their effects on film quality and stability are presented.

    Original languageEnglish (US)
    Pages (from-to)1556-1562
    Number of pages7
    JournalChemistry of Materials
    Volume6
    Issue number9
    StatePublished - 1994

    Profile

    Titanium
    Arthroscopy
    Sol-gels
    Hydrolysis
    Bibliography of Medicine
    Institutional Practice
    Carboxylic acids
    Acetic acid
    Silicates
    Casting
    Glass
    Thin films
    Acids
    Substrates
    Cortical Synchronization
    Blood Flow Velocity

    ASJC Scopus subject areas

    • Materials Chemistry
    • Materials Science(all)

    Cite this

    Application of controlled hydrolysis of titanium(IV) isopropoxide to produce sol-gel-derived thin films. / Dunuwila, Dilum D.; Gagliardi, Charles D.; Berglund, Kris A.

    In: Chemistry of Materials, Vol. 6, No. 9, 1994, p. 1556-1562.

    Research output: Contribution to journalArticle

    Dunuwila, Dilum D.; Gagliardi, Charles D.; Berglund, Kris A. / Application of controlled hydrolysis of titanium(IV) isopropoxide to produce sol-gel-derived thin films.

    In: Chemistry of Materials, Vol. 6, No. 9, 1994, p. 1556-1562.

    Research output: Contribution to journalArticle

    @article{80bd40514bee4b23b348a4897a376f41,
    title = "Application of controlled hydrolysis of titanium(IV) isopropoxide to produce sol-gel-derived thin films",
    abstract = "A variety of porous optically transparent titanium carboxylate films that can be supported on silicate glass substrates have been developed. These films were made by spin casting polymeric solutions of titanium carboxylates processed using sol-gel techniques. The stability and the quality of these films have been qualitatively correlated to the extent of control of hydrolysis exerted by carboxylate modification of the precursor titanium(IV) isopropoxide. A series of carboxylic acids ranging from acetic acid to myristic acid has been used, and their effects on film quality and stability are presented.",
    author = "Dunuwila, {Dilum D.} and Gagliardi, {Charles D.} and Berglund, {Kris A.}",
    year = "1994",
    volume = "6",
    pages = "1556--1562",
    journal = "Chemistry of Materials",
    issn = "0897-4756",
    publisher = "American Chemical Society",
    number = "9",

    }

    TY - JOUR

    T1 - Application of controlled hydrolysis of titanium(IV) isopropoxide to produce sol-gel-derived thin films

    AU - Dunuwila,Dilum D.

    AU - Gagliardi,Charles D.

    AU - Berglund,Kris A.

    PY - 1994

    Y1 - 1994

    N2 - A variety of porous optically transparent titanium carboxylate films that can be supported on silicate glass substrates have been developed. These films were made by spin casting polymeric solutions of titanium carboxylates processed using sol-gel techniques. The stability and the quality of these films have been qualitatively correlated to the extent of control of hydrolysis exerted by carboxylate modification of the precursor titanium(IV) isopropoxide. A series of carboxylic acids ranging from acetic acid to myristic acid has been used, and their effects on film quality and stability are presented.

    AB - A variety of porous optically transparent titanium carboxylate films that can be supported on silicate glass substrates have been developed. These films were made by spin casting polymeric solutions of titanium carboxylates processed using sol-gel techniques. The stability and the quality of these films have been qualitatively correlated to the extent of control of hydrolysis exerted by carboxylate modification of the precursor titanium(IV) isopropoxide. A series of carboxylic acids ranging from acetic acid to myristic acid has been used, and their effects on film quality and stability are presented.

    UR - http://www.scopus.com/inward/record.url?scp=0001479783&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=0001479783&partnerID=8YFLogxK

    M3 - Article

    VL - 6

    SP - 1556

    EP - 1562

    JO - Chemistry of Materials

    T2 - Chemistry of Materials

    JF - Chemistry of Materials

    SN - 0897-4756

    IS - 9

    ER -