Characterization and functional assessment of a cobalt(III)-oxo cubane cluster water oxidation catalyst immobilized on ITO

Hao Yuan, De'Andra L. Newton, Luke A. Seymour, Anja Metz, Donald Cropek, Alvin A. Holder, Robert Y. Ofoli

    Research output: Contribution to journalArticle

    • 7 Citations

    Abstract

    A cobalt(III) oxo cubane water oxidation catalyst, a structural mimic of the natural oxygen-evolving center, was immobilized on indium tin oxide (ITO) to promote recycling. The structure and composition of the complex were characterized by Fourier transform-infrared (FT-IR) spectroscopy, surface FT-IR, scanning electron microscopy, and energy dispersive X-ray spectroscopy. Cyclic voltammetry was used to assess catalyst functionality, stability, and recyclability. The results showed that this catalyst can be successfully immobilized on ITO, and that the complex functions in the same manner as the free catalyst in solution. This separation of synthesis and immobilization has great potential for optimizing heterogeneous catalysts.

    Original languageEnglish (US)
    Pages (from-to)76-80
    Number of pages5
    JournalCatalysis Communications
    Volume56
    DOIs
    StatePublished - Nov 5 2014

    Profile

    Catalysts
    Afferent Loop Syndrome
    Tin oxides
    Indium
    Cobalt
    Oxidation
    Water
    Avian Leukosis
    Functional assessment
    Cyclic voltammetry
    Fourier transform infrared spectroscopy
    Recycling
    Fourier transforms
    Infrared radiation
    Scanning electron microscopy
    Oxygen
    Chemical analysis
    Edema Disease of Swine
    Conjunctival Diseases
    Bibliography of Medicine

    Keywords

    • Artificial photosynthesis
    • Catalyst recycle
    • Cyclic voltammetry
    • Electrochemical deposition

    ASJC Scopus subject areas

    • Catalysis
    • Process Chemistry and Technology
    • Chemistry(all)

    Cite this

    Characterization and functional assessment of a cobalt(III)-oxo cubane cluster water oxidation catalyst immobilized on ITO. / Yuan, Hao; Newton, De'Andra L.; Seymour, Luke A.; Metz, Anja; Cropek, Donald; Holder, Alvin A.; Ofoli, Robert Y.

    In: Catalysis Communications, Vol. 56, 05.11.2014, p. 76-80.

    Research output: Contribution to journalArticle

    Yuan, Hao; Newton, De'Andra L.; Seymour, Luke A.; Metz, Anja; Cropek, Donald; Holder, Alvin A.; Ofoli, Robert Y. / Characterization and functional assessment of a cobalt(III)-oxo cubane cluster water oxidation catalyst immobilized on ITO.

    In: Catalysis Communications, Vol. 56, 05.11.2014, p. 76-80.

    Research output: Contribution to journalArticle

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    abstract = "A cobalt(III) oxo cubane water oxidation catalyst, a structural mimic of the natural oxygen-evolving center, was immobilized on indium tin oxide (ITO) to promote recycling. The structure and composition of the complex were characterized by Fourier transform-infrared (FT-IR) spectroscopy, surface FT-IR, scanning electron microscopy, and energy dispersive X-ray spectroscopy. Cyclic voltammetry was used to assess catalyst functionality, stability, and recyclability. The results showed that this catalyst can be successfully immobilized on ITO, and that the complex functions in the same manner as the free catalyst in solution. This separation of synthesis and immobilization has great potential for optimizing heterogeneous catalysts.",
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    AU - Metz,Anja

    AU - Cropek,Donald

    AU - Holder,Alvin A.

    AU - Ofoli,Robert Y.

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