Controlling amine receptor group density on aluminum oxide surfaces by mixed silane self assembly

Ilsoon Lee, Richard P. Wool

Research output: Research - peer-reviewArticle

  • 33 Citations

Abstract

To estimate adhesion at polymer-solid interfaces, model substrates with varying -NH2 density on Al2O3 were prepared by a self-assembly of mixed amine terminated silanes (AS) and methyl terminated silanes (MS). The density of -NH2 groups on Al2O3 was varied by changing the mol.% of AS and MS in solution. The model surfaces were characterized by means of X-ray photoelectron spectroscopy (XPS), contact angle measurements, atomic force microscopy (AFM), and mechanical tests with polymers. The analysis of the competitive coadsorption kinetic model showed that MS adsorbed two times faster than AS on aluminum surfaces. The surface energetics of Al2O3 was controlled by the mixed silane treatments from hydrophobic and low energetic to hydrophilic and high energetic surfaces.

LanguageEnglish (US)
Pages94-100
Number of pages7
JournalThin Solid Films
Volume379
Issue number1-2
DOIs
StatePublished - Dec 8 2000
Externally publishedYes

Profile

Silanes
Self assembly
Amines
Aluminum
Oxides
Aluminum Oxide
silanes
self assembly
amines
aluminum oxides
Polymers
polymers
Angle measurement
Contact angle
Atomic force microscopy
Adhesion
X ray photoelectron spectroscopy
Kinetics
Substrates
adhesion

ASJC Scopus subject areas

  • Surfaces, Coatings and Films
  • Condensed Matter Physics
  • Surfaces and Interfaces

Cite this

Controlling amine receptor group density on aluminum oxide surfaces by mixed silane self assembly. / Lee, Ilsoon; Wool, Richard P.

In: Thin Solid Films, Vol. 379, No. 1-2, 08.12.2000, p. 94-100.

Research output: Research - peer-reviewArticle

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