Electrochemical modeling of single particle intercalation battery materials with different thermodynamics

    Research output: Contribution to journalArticle

    • 16 Citations

    Abstract

    Current-voltage relations of a single intercalation battery electrode particle were modeled with the step current, step voltage, linear sweep voltage, and sinusoidal current signals. A solid solution with constant diffusivity, a solid solution with variable diffusivity, and a phase transformation material were considered for their thermodynamic and kinetic evaluations based on the regular solution model and the generalized Poisson-Nernst-Planck equations. The numerical simulation results were compared with known, small-signal solutions and experimental data throughout the article.

    Original languageEnglish (US)
    Pages (from-to)6534-6553
    Number of pages20
    JournalJournal of Power Sources
    Volume196
    Issue number15
    DOIs
    StatePublished - Aug 1 2011

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    Keywords

    • Current-voltage relation
    • Intercalation battery
    • Phase transformation
    • Poisson-Nernst-Planck
    • Regular solution
    • Single particle

    ASJC Scopus subject areas

    • Electrical and Electronic Engineering
    • Energy Engineering and Power Technology
    • Renewable Energy, Sustainability and the Environment
    • Physical and Theoretical Chemistry

    Cite this

    Electrochemical modeling of single particle intercalation battery materials with different thermodynamics. / Lai, Wei.

    In: Journal of Power Sources, Vol. 196, No. 15, 01.08.2011, p. 6534-6553.

    Research output: Contribution to journalArticle

    Lai, Wei / Electrochemical modeling of single particle intercalation battery materials with different thermodynamics.

    In: Journal of Power Sources, Vol. 196, No. 15, 01.08.2011, p. 6534-6553.

    Research output: Contribution to journalArticle

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