Polymer nanocomposites processed via self-assembly through introduction of nanoparticles, nanosheets, and nanofibers

Iman Harsini, Muhammad Maqbool Sadiq, Parviz Soroushian, Anagi M. Balachandra

    Research output: Contribution to journalArticle

    Abstract

    Nanocomposites offer the theoretical potential to achieve mechanical properties surpassing those of conventional (micro-scale) composites. The underlying reasons for the high potential of nanocomposites include the uniquely high mechanical attributes of nano-scale reinforcement, effective control of defect size and growth by nano-spaced interfaces, and interactions between the polymer matrix and the large surface areas of nanomaterials. Attempts to produce nanocomposites via conventional processing techniques have encountered challenges associated with thorough dispersion and effective interfacial interactions of nano-scale reinforcement with the polymer matrix. In order to address these challenges, materials were processed into polymer nanocomposites via electrostatically driven layer-by-layer self-assembly. Electrostatically dispersed nanomaterials and oppositely charged polyelectrolytes were sequentially built upon a substrate (cellular scaffold). The self-assembled nanocomposites, after complementary cross-linking, provided a unique balance of strength and ductility, which surpassed those of conventional (micro-scale) composites. Self-assembly was found to be an effective approach to producing nanocomposites embodying uniformly dispersed nanomaterials with controlled interfacial interactions. This approach is highly versatile and enables introduction of diverse nanomaterials into polymer nanocomposites. The work reported herein evaluated introduction of diverse categories of nanomaterials incorporating nanoparticles, nanosheets, nanotubes, and nanofibers. This investigation also evaluated the potential for a biomimetic approach to processing of light-weight structural systems by self-assembly of polymer nanocomposites onto cellular scaffolds.

    Original languageEnglish (US)
    Pages (from-to)1969-1980
    Number of pages12
    JournalJournal of Materials Science
    Volume52
    Issue number4
    DOIs
    StatePublished - Feb 1 2017

    Profile

    Laryngeal Mucosa
    Nanocomposites
    Biological Therapy
    Nanostructured materials
    Surgical Hemostasis
    Self assembly
    Polymers
    Accessory Nerve
    Cyanoacrylates
    Nanosheets
    Myosins
    Nanofibers
    Polymer matrix
    Scaffolds
    Composite materials
    Reinforcement
    Nanoparticles
    Edema Disease of Swine
    Erythrasma
    Acyl Carrier Protein

    ASJC Scopus subject areas

    • Materials Science(all)
    • Mechanics of Materials
    • Mechanical Engineering

    Cite this

    Polymer nanocomposites processed via self-assembly through introduction of nanoparticles, nanosheets, and nanofibers. / Harsini, Iman; Sadiq, Muhammad Maqbool; Soroushian, Parviz; Balachandra, Anagi M.

    In: Journal of Materials Science, Vol. 52, No. 4, 01.02.2017, p. 1969-1980.

    Research output: Contribution to journalArticle

    Harsini, Iman; Sadiq, Muhammad Maqbool; Soroushian, Parviz; Balachandra, Anagi M. / Polymer nanocomposites processed via self-assembly through introduction of nanoparticles, nanosheets, and nanofibers.

    In: Journal of Materials Science, Vol. 52, No. 4, 01.02.2017, p. 1969-1980.

    Research output: Contribution to journalArticle

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