Unusual decrease in conductivity upon hydration in acceptor doped, microcrystalline ceria

William C. Chueh, Chih Kai Yang, Carol M. Garland, Wei Lai, Sossina M. Haile

    Research output: Research - peer-reviewArticle

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    Abstract

    The impact of hydration on the transport properties of microcrystalline Sm0.15Ce0.85O1.925 has been examined. Dense, polycrystalline samples were obtained by conventional ceramic processing and the grain boundary regions were found, by high resolution transmission electron microscopy, to be free of impurity phases. Impedance spectroscopy measurements were performed over the temperature range 250 to 650 °C under dry, H 2O-saturated, and D2O-saturated synthetic air; and over the temperature range 575 to 650 °C under H2-H2O atmospheres. Under oxidizing conditions humidification by either H2O or D2O caused a substantial increase in the grain boundary resistivity, while leaving the bulk (or grain interior) properties unchanged. This unusual behavior, which was found to be both reversible and reproducible, is interpreted in terms of the space-charge model, which adequately explains all the features of the measured data. It is found that the space-charge potential increases by 5-7 mV under humidification, in turn, exacerbating oxygen vacancy depletion in the space-charge regions and leading to the observed reduction in grain boundary conductivity. It is proposed that the heightened space-charge potential reflects a change in the relative energetics of vacancy creation in the bulk and at the grain boundary interfaces as a result of water uptake into the grain boundary core. Negligible bulk water uptake is detected under both oxidizing and reducing conditions.

    LanguageEnglish (US)
    Pages6442-6451
    Number of pages10
    JournalPhysical Chemistry Chemical Physics
    Volume13
    Issue number14
    DOIs
    StatePublished - Apr 14 2011

    Profile

    hydration
    grain boundaries
    conductivity
    Cerium compounds
    Hydration
    Grain boundaries
    space charge
    Electric space charge
    water
    temperature
    Water
    Temperature
    depletion
    transport properties
    impedance
    ceramics
    atmospheres
    impurities
    transmission electron microscopy
    electrical resistivity

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Physics and Astronomy(all)

    Cite this

    Unusual decrease in conductivity upon hydration in acceptor doped, microcrystalline ceria. / Chueh, William C.; Yang, Chih Kai; Garland, Carol M.; Lai, Wei; Haile, Sossina M.

    In: Physical Chemistry Chemical Physics, Vol. 13, No. 14, 14.04.2011, p. 6442-6451.

    Research output: Research - peer-reviewArticle

    Chueh, William C. ; Yang, Chih Kai ; Garland, Carol M. ; Lai, Wei ; Haile, Sossina M./ Unusual decrease in conductivity upon hydration in acceptor doped, microcrystalline ceria. In: Physical Chemistry Chemical Physics. 2011 ; Vol. 13, No. 14. pp. 6442-6451
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